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安(an)康(kang)果殼活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan) 1. 活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)鉻(ge)(ge)(ge)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。鉻(ge)(ge)(ge)是電(dian)(dian)(dian)鍍中(zhong)用(yong)(yong)量(liang)較(jiao)大(da)的(de)(de)(de)(de)(de)(de)一(yi)種金屬原料，在(zai)(zai)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)中(zhong)六價鉻(ge)(ge)(ge)隨pH值(zhi)的(de)(de)(de)(de)(de)(de)不同分別(bie)以(yi)(yi)(yi)不同的(de)(de)(de)(de)(de)(de)形式存(cun)在(zai)(zai)。韓(han)(han)研活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)有(you)非常發(fa)達(da)(da)的(de)(de)(de)(de)(de)(de)微(wei)孔結構(gou)和(he)(he)較(jiao)高(gao)(gao)的(de)(de)(de)(de)(de)(de)比(bi)表(biao)面積，具有(you)極強的(de)(de)(de)(de)(de)(de)物理(li)(li)(li)(li)(li)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)能(neng)(neng)(neng)力，能(neng)(neng)(neng)有(you)效(xiao)地(di)(di)(di)(di)(di)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)中(zhong)的(de)(de)(de)(de)(de)(de)Cr（Ⅵ）.活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)的(de)(de)(de)(de)(de)(de)表(biao)面存(cun)在(zai)(zai)大(da)量(liang)的(de)(de)(de)(de)(de)(de)含(han)(han)(han)(han)(han)氧基(ji)(ji)團如羥基(ji)(ji)（-OH）、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)羧(suo)基(ji)(ji)（-COOH）等，它們都(dou)有(you)靜電(dian)(dian)(dian)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)功能(neng)(neng)(neng)，對(dui)Cr（Ⅵ）產生(sheng)(sheng)化(hua)學(xue)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)作(zuo)用(yong)(yong)。完全(quan)可(ke)以(yi)(yi)(yi)用(yong)(yong)于(yu)(yu)(yu)處(chu)理(li)(li)(li)(li)(li)電(dian)(dian)(dian)鍍廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)中(zhong)的(de)(de)(de)(de)(de)(de)Cr（Ⅵ），吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)后(hou)的(de)(de)(de)(de)(de)(de)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)可(ke)達(da)(da)到 排放標準。試驗(yan)表(biao)明(ming)：溶(rong)液(ye)中(zhong)Cr（Ⅵ）質量(liang)濃度(du)為50mg/L，pH＝3，吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)時間(jian)(jian)1.5h時，活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)的(de)(de)(de)(de)(de)(de)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)能(neng)(neng)(neng)和(he)(he)Cr（Ⅵ）的(de)(de)(de)(de)(de)(de)去(qu)(qu)(qu)除率(lv)(lv)(lv)均(jun)(jun)達(da)(da)到 效(xiao)果。.因(yin)此(ci)，利(li)用(yong)(yong)活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)鉻(ge)(ge)(ge)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)的(de)(de)(de)(de)(de)(de)過程是活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)對(dui)溶(rong)液(ye)中(zhong)Cr（Ⅵ）的(de)(de)(de)(de)(de)(de)物理(li)(li)(li)(li)(li)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)化(hua)學(xue)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)化(hua)學(xue)還(huan)原等綜合(he)作(zuo)用(yong)(yong)的(de)(de)(de)(de)(de)(de)結果。活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)鉻(ge)(ge)(ge)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)，吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)能(neng)(neng)(neng)穩定，處(chu)理(li)(li)(li)(li)(li)效(xiao)率(lv)(lv)(lv)高(gao)(gao)，操(cao)作(zuo)費用(yong)(yong)低，有(you)一(yi)定的(de)(de)(de)(de)(de)(de)社會效(xiao)益(yi)和(he)(he)經濟(ji)效(xiao)益(yi)。 2.活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)氰(qing)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。在(zai)(zai)工(gong)(gong)業(ye)生(sheng)(sheng)產中(zhong)，金銀的(de)(de)(de)(de)(de)(de)濕法(fa)提取、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)化(hua)學(xue)纖維的(de)(de)(de)(de)(de)(de)生(sheng)(sheng)產、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)煉焦、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)合(he)成氨、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)電(dian)(dian)(dian)鍍、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)煤氣生(sheng)(sheng)產等行業(ye)均(jun)(jun)使(shi)用(yong)(yong) 或副產 ，因(yin)而(er)(er)在(zai)(zai)生(sheng)(sheng)產過程中(zhong)必然(ran)要(yao)排放一(yi)定數量(liang)的(de)(de)(de)(de)(de)(de)含(han)(han)(han)(han)(han)氰(qing)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)用(yong)(yong)于(yu)(yu)(yu)凈化(hua)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)已有(you)相當(dang)(dang)(dang)(dang)長的(de)(de)(de)(de)(de)(de)歷(li)史(shi)，應用(yong)(yong)于(yu)(yu)(yu)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)氰(qing)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)的(de)(de)(de)(de)(de)(de)文獻報道也越來越多(duo).但(dan)由于(yu)(yu)(yu)CN_、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)HCN在(zai)(zai)活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)上(shang)的(de)(de)(de)(de)(de)(de)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)容量(liang)小(xiao)，一(yi)般為3mgCN/gAC～8mgCN/gAC因(yin)品(pin)種而(er)(er)異，在(zai)(zai)處(chu)理(li)(li)(li)(li)(li)成本上(shang)不合(he)算(suan)。 3. 活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)汞(gong)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)有(you)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)汞(gong)和(he)(he)含(han)(han)(han)(han)(han)汞(gong)化(hua)合(he)物的(de)(de)(de)(de)(de)(de)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)能(neng)(neng)(neng)，但(dan)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)能(neng)(neng)(neng)力有(you)限，只適(shi)宜于(yu)(yu)(yu)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)汞(gong)量(liang)低的(de)(de)(de)(de)(de)(de)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。如果含(han)(han)(han)(han)(han)汞(gong)的(de)(de)(de)(de)(de)(de)濃度(du)較(jiao)高(gao)(gao)，可(ke)以(yi)(yi)(yi)先用(yong)(yong)化(hua)學(xue)沉淀(dian)法(fa)處(chu)理(li)(li)(li)(li)(li)，處(chu)理(li)(li)(li)(li)(li)后(hou)含(han)(han)(han)(han)(han)汞(gong)約1mg/L，高(gao)(gao)時可(ke)達(da)(da)2-3mg/L，然(ran)后(hou)再用(yong)(yong)活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)做進(jin)一(yi)步的(de)(de)(de)(de)(de)(de)處(chu)理(li)(li)(li)(li)(li)。 4. 活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)酚(fen)(fen)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。含(han)(han)(han)(han)(han)酚(fen)(fen)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)廣泛來源于(yu)(yu)(yu)石油化(hua)工(gong)(gong)廠(chang)(chang)、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)樹脂廠(chang)(chang)、安(an)康(kang)當(dang)(dang)(dang)(dang)地(di)(di)(di)(di)(di)焦化(hua)廠(chang)(chang)和(he)(he)煉油化(hua)工(gong)(gong)廠(chang)(chang)。經實(shi)驗(yan)證明(ming)：韓(han)(han)研活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)對(dui)苯酚(fen)(fen)的(de)(de)(de)(de)(de)(de)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)能(neng)(neng)(neng)好，溫(wen)度(du)升(sheng)高(gao)(gao)不利(li)于(yu)(yu)(yu)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)，使(shi)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)容量(liang)減小(xiao)；但(dan)升(sheng)高(gao)(gao)溫(wen)度(du)達(da)(da)到吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)平衡(heng)的(de)(de)(de)(de)(de)(de)時間(jian)(jian)縮短。活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)的(de)(de)(de)(de)(de)(de)用(yong)(yong)量(liang)和(he)(he)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)時間(jian)(jian)存(cun)在(zai)(zai) 值(zhi)，在(zai)(zai)酸(suan)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)和(he)(he)中(zhong)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)條件下(xia)，去(qu)(qu)(qu)除率(lv)(lv)(lv)變(bian)化(hua)不大(da)；強堿(jian)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)條件下(xia)，苯酚(fen)(fen)去(qu)(qu)(qu)除率(lv)(lv)(lv)急劇(ju)下(xia)降，堿(jian)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)越強，吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)效(xiao)果越差。 5. 活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)甲(jia)醇廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。韓(han)(han)研活(huo)(huo)(huo)性(xing)(xing)(xing)(xing)(xing)(xing)(xing)(xing)炭(tan)(tan)(tan)(tan)(tan)(tan)(tan)可(ke)以(yi)(yi)(yi)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)甲(jia)醇，但(dan)吸(xi)(xi)(xi)(xi)(xi)(xi)附(fu)(fu)(fu)能(neng)(neng)(neng)力不強，只適(shi)宜于(yu)(yu)(yu)處(chu)理(li)(li)(li)(li)(li)含(han)(han)(han)(han)(han)甲(jia)醇量(liang)低的(de)(de)(de)(de)(de)(de)廢(fei)(fei)水(shui)(shui)(shui)(shui)(shui)。工(gong)(gong)程運行結果表(biao)明(ming)，可(ke)將(jiang)混(hun)合(he)液(ye)的(de)(de)(de)(de)(de)(de)COD從40mg/L降至(zhi)12mg/L以(yi)(yi)(yi)下(xia)，對(dui)甲(jia)醇的(de)(de)(de)(de)(de)(de)去(qu)(qu)(qu)除率(lv)(lv)(lv)達(da)(da)到93.16％～100％，其出(chu)水(shui)(shui)(shui)(shui)(shui)水(shui)(shui)(shui)(shui)(shui)質可(ke)以(yi)(yi)(yi)滿(man)足回用(yong)(yong)到鍋(guo)爐脫鹽水(shui)(shui)(shui)(shui)(shui)系統進(jin)水(shui)(shui)(shui)(shui)(shui)的(de)(de)(de)(de)(de)(de)水(shui)(shui)(shui)(shui)(shui)質要(yao)求。